Investigation of the Reactions Between Uranium Dioxide, Thorium Dioxide and Uranium Tetrafloride in the Liquid and Vapor Phase; A Project presented to the Department of Nuclear Engineering of the University of Florida in partial fulfillment of the Requirements for the Degree of Master of Engineering
Gainesville, FL: University of Florida, 1990. Presumed First Edition, First printing thus. Comb binding. vi, 75 pages. Clear plastic sheet in front of thesis cover. List of Figures. Abstract. Introduction. Experimental Description. Results. Conclusions, Appendices, and References. This work involved a literature survey, both theoretical and experimental methods and a review of current work. The experiment involved apparatus, procedure, sample description and post exposure analysis. The primary conclusion was that neither UO2 nor ThOs were suitable for use as structural or lining materials in exposure to pure UF4 in either the liquid or gas phase. However the results did prove the applicability of the phase diagram produced by Fonteneau and Lucas to the liquid phase reactions of these compounds, as well as proving the assumption that at the temperatures of interest in this study, corrosive reactions would proceed to equilibrium so rapidly as to make reaction kinetics relatively unimportant. More
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